129
Access to N-Difluoromethyl Amides, (Thio)Carbamates, Ureas, and Formamides
F. G. Zivkovic, G. Wycich, L. Liu, F. Schoenebeck*
J. Am. Chem. Soc. 2024, 146, 1276.
(highlighted in ChemistryViews)
124
Orthogonal Olefination with Organogermanes
A. Dahiya, M. D. Schoetz, F. Schoenebeck*
Angew. Chem. Int. Ed. 2023, 62, e202310380.
(highlighted in Org. Process Res. Dev. 2024, 28, 327.)
123
Machine Learning-Guided Development of Trialkylphosphine Ni(I) Dimers and Applications in Site-Selective Catalysis
T. M. Karl, S. Bouayad-Gervais, J. A. Hueffel, T. Sperger, S. Wellig, S. J. Kaldas, U. Dabranskaya, J. S. Ward, K. Rissanen, G. J. Tizzard, F. Schoenebeck*
J. Am. Chem. Soc. 2023, 145, 15414.
121
Rapid and Modular Access to Vinyl Cyclopropanes Enabled by Air-stable Palladium(I) Dimer Catalysis
M. Mendel, L. Gnägi, U. Dabranskaya, F. Schoenebeck*
Angew. Chem. Int. Ed. 2023, 62, e202211167.
(highlighted in Synfacts)
115
Modular Generation of (Iodinated) Polyarenes using Organogermane as Orthogonal Masking Group
T. Kreisel, M. Mendel, A. E. Queen, K. Deckers, D. Hupperich, J. Riegger, C. Fricke, F. Schoenebeck*
Angew. Chem. Int. Ed. 2022, 61, e202201475.
(highlighted by P. W. Seavill in Nat. Synth. 2022, DOI 10.1038/s44160-022-00062-z)
114
Air-Stable Pd(I) Dimer enabled Remote Functionalization: Access to Fluorinated 1,1-Diaryl Alkanes with Unprecedented Speed
G. Kundu, F. Opincal, T. Sperger, F. Schoenebeck*
Angew. Chem. Int. Ed. 2022, 61, e202113667.
(highlighted in ChemistryViews)
112
Direct C–H Dehydrogenative Germylation of Terminal Alkynes with Hydrogermanes
A. Dahiya, F. Schoenebeck*
Org. Lett. 2022, 24, 2728.
(highlighted in ChemistryViews)
98
Modular & Selective Arylation of Aryl Germanes (C-GeEt₃) over
C-Bpin, C-SiR₃ and Halogens enabled by Light-Activated Gold-Catalysis
G. J. Sherborne, A. G. Gevondian, I. Funes-Ardoiz, A. Dahiya, C. Fricke, F. Schoenebeck*
Angew. Chem. Int. Ed. 2020, 59, 15543.
(highlighted by S. Davey in Nat. Rev. Chem. 2020, 4, 333.)
88
Straightforward Access to N-Trifluoromethyl Amides, Carbamates, Thiocarbamates and Ureas
T. Scattolin, S. Bouayad-Gervais, F. Schoenebeck*
Nature 2019, 573, 102.
(Patent application filed. See also "News & Views" by J. Clayden (Nature 2019, 573, 37), C&En News highlight & blog by D. Lowe)
86
Arylation of Axially Chiral Phosphorothioate Salts via Dinuclear Pd(I) Catalysis
X.-Y. Chen, M.-P. Pu, H.-G. Cheng, T. Sperger, F. Schoenebeck*
Angew. Chem. Int. Ed. 2019, 58, 11395.
(featured on The Cyclo Edition podcast)
78
Modular Functionalization of Arenes in a Triply Selective Sequence: Rapid C(sp²) and C(sp³) Coupling of C-Br, C-OTf & C-Cl enabled by a Single Pd(I) Dimer
S. T. Keaveney, G. Kundu, F. Schoenebeck*
Angew. Chem. Int. Ed. 2018, 57, 12573.
(selected as very important paper (VIP) & highlighted in Synfacts)
70
Direct Synthesis of Acyl Fluorides from Carboxylic Acids with the Bench-Stable Solid Reagent (Me₄N)SCF₃
T. Scattolin, K. Deckers, F. Schoenebeck*
Org. Lett. 2017, 19, 5740.
(highlighted in C&En News and ChemistryViews)
68
Palladium(I) Dimer Enabled Extremely Rapid and Chemoselective Alkylation of Aryl Bromides over Triflates and Chlorides in Air
I. Kalvet, T. Sperger, T. Scattolin, G. Magnin, F. Schoenebeck*
Angew. Chem. Int. Ed. 2017, 56, 7078.
(highlighted in Synfacts)
66
Understanding the Unusual Reduction Mechanism of Pd(II) to Pd(I): Uncovery of Hidden Species and Implications in Catalytic Cross-Coupling Reactions
C. C. C. Johansson Seechurn, T. Sperger, T. G. Scrase, F. Schoenebeck,* T. J. Colacot*
J. Am. Chem. Soc. 2017, 139, 5194.
(highlighted in C&En News)
64
Rapid Room Temperature Chemoselective C(sp²)-(Csp²) Coupling of Poly(pseudo)halogenated Arenes enabled by Pd(I) Catalysis in Air
I. Kalvet, G. Magnin, F. Schoenebeck*
Angew. Chem. Int. Ed. 2017, 56, 1581.
(highlighted in Synfacts)
63
Efficient Synthesis of Trifluoromethyl Amines (N-CF₃) via a Formal Umpolung Strategy from the Bench-Stable Precursor (Me₄N)SCF₃
T. Scattolin, K. Deckers, F. Schoenebeck*
Angew. Chem. Int. Ed. 2017, 56, 221.
(highlighted by Derek Lowe & belongs to the top 20 most downloaded articles in 2016 - 2018)
36
Computational Ligand Design for the Reductive Elimination of ArCF₃ from a Small Bite Angle Pd(II)-Complex: Remarkable Effect of a Perfluoroalkyl Phosphine
M. C. Nielsen, K. J. Bonney, F. Schoenebeck*
Angew. Chem. Int. Ed. 2014, 53, 5903.
(highlighted in Nature Chemistry 2014, 6, 558.)
23
Redox Reactions in Palladium Catalysis: On the Accelerating and/or Inhibiting Effects of Copper and Silver Salt Additives in Cross-Coupling Chemistry Involving Electron-Rich Phosphine Ligands
M. Aufiero, F. Proutiere, F. Schoenebeck*
Angew. Chem. Int. Ed. 2012, 51, 7226.
(selected as very important paper (VIP) & highlighted in Chimia and Angew. Chem. Int. Ed. 2012, 51, 10448.)
19
Electron Transfer to Benzenes by Photoactivated Neutral Organic Electron Donors
E. Cahard, F. Schoenebeck*, J. Garnier, S. P. Y. Cutulic, S. Zhou, J. A. Murphy*
Angew. Chem. Int. Ed. 2012, 51, 3673.
(highlighted in C&En News)
14
Expanding the chemical space for push-pull chromophores by non-concerted [2+2] and [4+2] cycloadditions: access to a highly functionalised 6,6-dicyanopentafulvene with an intense, low-energy charge-transfer band
G. Jayamurugan, J.-P.l Gisselbrecht, C. Boudon, F. Schoenebeck*, W. B. Schweizer, B. Bernet, F. Diederich*
Chem. Commun. 2011, 47, 4520.
-
Nature of Intermediates in Organo-SOMO Catalysis of α-Arylation of Aldehydes, J. M. Um, O. Gutierrez, F. Schoenebeck, K. N. Houk*, D. W. C. MacMillan*, J. Am. Chem. Soc. 2010, 132, 6001.
-
Ligand-Controlled Regioselectivity in Palladium-Catalyzed Cross Coupling Reactions, F. Schoenebeck*, K. N. Houk*, J. Am. Chem. Soc. 2010, 132, 2496.
-
Reductions of Challenging Organic Substrates by a Nickel Complex of a Noninnocent Crown Carbene Ligand, N. J. Findlay, S. R. Park, F. Schoenebeck, E. Cahard, S.-Z. Zhou, L. E. A. Berlouis, M. D. Spicer, T. Tuttle, J. A. Murphy*, J. Am. Chem. Soc. 2010, 132, 15462.
-
Computational Study of Factors Controlling the Boat and Chair Transition States of Ireland-Claisen Rearrangements, S. Gül, F. Schoenebeck, V. Aviyente, K. N. Houk*, J. Org. Chem. 2010, 75, 2115.
-
Reactivity and Regioselectivity in 1,3-Dipolar Cycloadditions of Azides to Strained Alkenes and Alkynes: A Computational Study, F. Schoenebeck, D. H. Ess, G. O. Jones, K. N. Houk*, J. Am. Chem. Soc. 2009, 131, 8121.
-
Theoretical Bond Dissociation Energies of Halo-Heterocycles: Trends and Relationships to Regioselectivity in Palladium-Catalyzed Cross-Coupling Reactions, Y. Garcia, F. Schoenebeck, C. Y. Legault, C. A. Merlic*, K. N. Houk*, J. Am. Chem. Soc. 2009, 131, 6632.
-
Theoretical Study of the Catalysis of Cyanohydrin Formation by the Cyclic Dipeptide Catalyst cyclo[(S)-His-(S)-Phe], F. Schoenebeck, K. N. Houk, J. Org. Chem. 2009, 74,1464.
-
One-Carbon Extrusion from a Tetraazafulvalene – Isolation of Aldehydes and a Study of Their Origin, J. A. Murphy*, F. Schoenebeck, N. J. Findlay, D. W. Thomson, S.-Z. Zhou, J. Garnier, J. Am. Chem. Soc. 2009, 131, 6475.
-
Super-Electron Donors: Bis-pyridinylidene Formation by Base Treatment of Pyridinium Salts, J. A. Murphy*, J. Garnier, S. R. Park, F. Schoenebeck, S.-Z. Zhou, A. T. Turner, Org. Lett. 2008, 6, 1227.
-
Reductive Cleavage of Sulfones and Sulfonamides by a Neutral Organic Super-Electron-Donor (S.E.D.) Reagent, F. Schoenebeck, J. A. Murphy*, S.-Z. Zhou, Y. Uenoyama, Y. Miclo, T. Tuttle, J. Am. Chem. Soc. 2007, 129, 13368.
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The Generation of Aryl Anions by Double Electron Transfer to Aryl Iodides from a Neutral Ground-State Organic Super Electron Donor (S.E.D.), J. A. Murphy*, S.-Z. Zhou, D. W. Thomson, F. Schoenebeck, M. Mahesh, S. R. Park, T. Tuttle, L. E. A. Berlouis, Angew. Chem. Int. Ed. 2007, 46, 5178.
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First Organophosphorus Radical-mediated Cyclisations To Afford Medium-sized Rings: 8-membered Lactones and 7- and 8-membered Lactams, S. Lang, M. Corr, N. Muir, T. A. Khan, F. Schönebeck, J. A. Murphy*, A. C. Williams, A. H. Payne, Tetrahedron Letters 2005, 46, 4027.