98
Modular & Selective Arylation of Aryl Germanes (C-GeEt3) over C-Bpin, C-SiR3 and Halogens enabled by Light-Activated Gold-Catalysis
G. J. Sherborne, A. G. Gevondian, I. Funes-Ardoiz, A. Dahiya, C. Fricke, F. Schoenebeck*
Angew. Chem. Int. Ed 2020, 59, 15543.
(highlighted by S. Davey in Nat. Rev. Chem. 2020, doi.org/10.1038/s41570-020-0207-y)
88
Straightforward Access to N-Trifluoromethyl Amides, Carbamates, Thiocarbamates and Ureas
T. Scattolin, S. Bouayad-Gervais, F. Schoenebeck*
Nature 2019, 573, 102.
(Patent application filed. See also "News & Views" by J. Clayden (Nature 2019, 573, 37), C&En News highlight & blog by D. Lowe)
78
70
Direct Synthesis of Acyl Fluorides from Carboxylic Acids with the Bench-Stable Solid Reagent (Me4N)SCF3
T. Scattolin, K. Deckers, F. Schoenebeck*
Org. Lett. 2017, 19, 5740.
(highlighted in C&En News and ChemistryViews)
68
Palladium(I) Dimer Enabled Extremely Rapid and Chemoselective Alkylation of Aryl Bromides over Triflates and Chlorides in Air
I. Kalvet, T. Sperger, T. Scattolin, G. Magnin, F. Schoenebeck*
Angew. Chem. Int. Ed. 2017, 56, 7078.
(highlighted in Synfacts)
66
Understanding the Unusual Reduction Mechanism of Pd(II) to Pd(I): Uncovery of Hidden Species and Implications in Catalytic Cross-Coupling Reactions
C. C. C. Johansson Seechurn, T. Sperger, T. G. Scrase, F. Schoenebeck,* T. J. Colacot*
J. Am. Chem. Soc. 2017, 139, 5194.
64
Rapid Room Temperature Chemoselective Csp2-Csp2 Coupling of Poly(pseudo)halogenated Arenes enabled by Pd(I) Catalysis in Air
I. Kalvet, G. Magnin, F. Schoenebeck*
Angew. Chem. Int. Ed. 2017, 56,1581.
(highlighted in Synfacts)
63
Efficient Synthesis of Trifluoromethyl Amines (N-CF3) via a Formal Umpolung Strategy from the Bench-Stable Precursor (Me4N)SCF3
T. Scattolin, K. Deckers, F. Schoenebeck*
Angew. Chem. Int. Ed. 2017, 56, 221.
(highlighted by Derek Lowe & belongs to the top 20 most downloaded articles in 2016 - 2018)
36
Computational Ligand Design for the Reductive Elimination of ArCF3 from a Small Bite Angle Pd(II)-Complex: Remarkable Effect of a Perfluoroalkyl Phosphine
M. C. Nielsen, K. J. Bonney, F. Schoenebeck*
Angew. Chem. Int. Ed. 2014, 53, 5903.
(highlighted in Nature Chemistry 2014, 6, 558)
23
Redox Reactions in Palladium Catalysis: On the Accelerating and/or Inhibiting Effects of Copper and Silver Salt Additives in Cross-Coupling Chemistry Involving Electron-Rich Phosphine Ligands
M. Aufiero, F. Proutiere, F. Schoenebeck*
Angew. Chem. Int. Ed. 2012, 51, 7226.
(selected as very important paper (VIP) & highlighted in Chimia and Angew. Chemie Int. Ed. 2012, 51, 10448)
14
Expanding the chemical space for push-pull chromophores by non-concerted [2+2] and [4+2] cycloadditions: access to a highly functionalised 6,6-dicyanopentafulvene with an intense, low-energy charge-transfer band
G. Jayamurugan, J.-P.l Gisselbrecht, C. Boudon, F. Schoenebeck*, W. B. Schweizer, B. Bernet, F. Diederich*
Chem. Commun. 2011, 47, 4520.
Previous Publications
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Nature of Intermediates in Organo-SOMO Catalysis of α-Arylation of Aldehydes, J. M. Um, O. Gutierrez, F. Schoenebeck, K. N. Houk*, D. W. C. MacMillan*, J. Am. Chem. Soc. 2010, 132, 6001.
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Ligand-Controlled Regioselectivity in Palladium-Catalyzed Cross Coupling Reactions, F. Schoenebeck*, K. N. Houk*, J. Am. Chem. Soc. 2010, 132, 2496.
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Reductions of Challenging Organic Substrates by a Nickel Complex of a Noninnocent Crown Carbene Ligand, N. J. Findlay, S. R. Park, F. Schoenebeck, E. Cahard, S.-Z. Zhou, L. E. A. Berlouis, M. D. Spicer, T. Tuttle, J. A. Murphy*, J. Am. Chem. Soc. 2010, 132, 15462.
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Computational Study of Factors Controlling the Boat and Chair Transition States of Ireland-Claisen Rearrangements, S. Gül, F. Schoenebeck, V. Aviyente, K. N. Houk*, J. Org. Chem. 2010, 75, 2115.
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Reactivity and Regioselectivity in 1,3-Dipolar Cycloadditions of Azides to Strained Alkenes and Alkynes: A Computational Study, F. Schoenebeck, D. H. Ess, G. O. Jones, K. N. Houk*, J. Am. Chem. Soc. 2009, 131, 8121.
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Theoretical Bond Dissociation Energies of Halo-Heterocycles: Trends and Relationships to Regioselectivity in Palladium-Catalyzed Cross-Coupling Reactions, Y. Garcia, F. Schoenebeck, C. Y. Legault, C. A. Merlic*, K. N. Houk*, J. Am. Chem. Soc. 2009, 131, 6632.
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Theoretical Study of the Catalysis of Cyanohydrin Formation by the Cyclic Dipeptide Catalyst cyclo[(S)-His-(S)-Phe], F. Schoenebeck, K. N. Houk, J. Org. Chem. 2009, 74,1464.
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One-Carbon Extrusion from a Tetraazafulvalene – Isolation of Aldehydes and a Study of Their Origin, J. A. Murphy*, F. Schoenebeck, N. J. Findlay, D. W. Thomson, S.-Z. Zhou, J. Garnier, J. Am. Chem. Soc. 2009, 131, 6475.
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Super-Electron Donors: Bis-pyridinylidene Formation by Base Treatment of Pyridinium Salts, J. A. Murphy*, J. Garnier, S. R. Park, F. Schoenebeck, S.-Z. Zhou, A. T. Turner, Org. Lett. 2008, 6, 1227.
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Reductive Cleavage of Sulfones and Sulfonamides by a Neutral Organic Super-Electron-Donor (S.E.D.) Reagent, F. Schoenebeck, J. A. Murphy*, S.-Z. Zhou, Y. Uenoyama, Y. Miclo, T. Tuttle, J. Am. Chem. Soc. 2007, 129, 13368.
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The Generation of Aryl Anions by Double Electron Transfer to Aryl Iodides from a Neutral Ground-State Organic Super Electron Donor (S.E.D.), J. A. Murphy*, S.-Z. Zhou, D. W. Thomson, F. Schoenebeck, M. Mahesh, S. R. Park, T. Tuttle, L. E. A. Berlouis, Angew. Chem. Int. Ed. 2007, 46, 5178.
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First Organophosphorus Radical-mediated Cyclisations To Afford Medium-sized Rings: 8-membered Lactones and 7- and 8-membered Lactams, S. Lang, M. Corr, N. Muir, T. A. Khan, F. Schönebeck, J. A. Murphy*, A. C. Williams, A. H. Payne, Tetrahedron Letters 2005, 46, 4027.